If you mean 'tools' in winbox, you're not going to find it there. You can only configure it by CLI:
hit 'New terminal' from the menu list on the left and in the terminal window type 'tool userman' - it's all in the wiki (wiki.mikrotik.com).
To check out userman 4, be sure to install the test version
http://mikrotik.com/download/userman-test-4.6.npk
http://routerip/username will not be accessible until you've properly setup userman; again check out the wiki.