Didn't see that IP on your facebook IP address list. Anyway, I just want to share here how I setup my filtering and will use facebook as an example of the site to be filtered here since we're talking facebook as the subject.
My filter rule
1 ;;; block fb
chain=forward src-address-list=!fwall-x dst-address-list=fb
action=reject reject-with=icmp-network-unreachable
My Address list
IP addresses of facebook that I am curently blocking
# LIST ADDRESS
0 fb 69.171.224.37
1 fb 69.171.242.11
2 fb 66.220.149.11
3 fb 66.220.158.11
4 fb 69.171.229.11
5 fb 69.171.224.53
6 fb 69.171.234.64
7 fb 66.220.146.94
8 fb 69.171.229.70
9 fb 66.220.149.88
10 fb 69.171.234.37
11 fb 69.171.234.21
12 fb 69.171.228.70
13 fb 69.171.229.74
14 fb 66.220.149.94
15 fb 69.171.228.74
16 fb 69.171.234.69
17 fb 66.220.146.101
18 fb 69.171.228.40
19 fb 69.171.224.64
20 fb 69.171.228.14
21 fb 66.220.147.88
22 fb 69.171.237.16
23 fb 69.171.237.32
24 fb 66.220.152.16
25 fb 66.220.158.70
26 fb 69.171.247.21
27 fb 69.171.224.36
28 fb 69.171.234.39
29 fb 69.171.228.72
30 fb 69.171.234.23
31 fb 69.171.237.20
32 fb 69.171.237.36
33 fb 69.171.229.18
34 fb 69.171.228.76
IP addresses of users that I want to have access to facebook
# LIST ADDRESS
0 ;;; user1
fwall-x 192.168.1.11
1 ;;; user2
fwall-x 192.168.1.28
2 ;;; rdc
fwall-x 192.168.1.25
As you can see I've created two address-list group, one for facebook addresses that I'm blocking and one for users that I am allowing to access facebook.
I then added a filter rule that says, everyone that is trying to access facebook will be blocked except for the addresses listed in the address-list named fwall-x.
I'm doing it this way so I will only have a single rule on my filter list which is practically easier to manage/maintain. And if I want to remove or allow a user's access to facebook then I just have to add it to the allowed list. Also, if want to block additional facebook ip then I just have to add that ip address to the fb address-list group. Oh, don't forget that comment too as it will help you with identifying who has access to what.
Also, if you want to block the entirety of facebook this might interest you. Take note of the Network Resources section as you will see their assigned network block.
http://whois.arin.net/rest/customer/C02001848
http://whois.arin.net/rest/customer/C02107106
http://whois.arin.net/rest/customer/C02107153
http://whois.arin.net/rest/customer/C02156967
http://whois.arin.net/rest/customer/C02738182
Good luck!