Is it possible to assign static route to PPTP Client? Because, we also need to send printing to local network printer.

Currently, all routing was throw to remote gateway (0.0.0.0 to x.x.x.x remote gateway)

Can add we add particular routing on PPTP Client, For example
10.120.10.0 to x.x.x.x remote gateway
10.10.10.0 to x.x.x.x remote gateway
and for the rest we send to local gateway.

Please give me some guidance.

yes you can do it easily by some route command.
first step unchecked your Default Route from your PPTP Connection on your router then add default route for your Internet Access with your PPTP Connection and set Distance greater than 2 , and after create route for internet access you must create other route for your local network(with different subnet ) and set distance to 1 .
you can more explain your project for give better answer.

Thank you Tavanajafar,

You can see Route Print as below, Bold text is default router to remote gateway that why user could not print to local network.

IPv4 Route Table
===========================================================================
Active Routes:
Network Destination Netmask Gateway Interface Metric
0.0.0.0 0.0.0.0 192.168.1.1 192.168.1.64 4245
0.0.0.0 0.0.0.0 On-link 172.16.1.136 21 --> Default Router
127.0.0.0 255.0.0.0 On-link 127.0.0.1 4531
127.0.0.1 255.255.255.255 On-link 127.0.0.1 4531
127.255.255.255 255.255.255.255 On-link 127.0.0.1 4531
172.16.1.136 255.255.255.255 On-link 172.16.1.136 276
182.52.142.119 255.255.255.255 192.168.1.1 192.168.1.64 4246
192.168.1.0 255.255.255.0 On-link 192.168.1.64 4501
192.168.1.64 255.255.255.255 On-link 192.168.1.64 4501
192.168.1.255 255.255.255.255 On-link 192.168.1.64 4501
192.168.112.0 255.255.255.0 On-link 192.168.112.1 4501
192.168.112.1 255.255.255.255 On-link 192.168.112.1 4501
192.168.112.255 255.255.255.255 On-link 192.168.112.1 4501
192.168.206.0 255.255.255.0 On-link 192.168.206.1 4501
192.168.206.1 255.255.255.255 On-link 192.168.206.1 4501
192.168.206.255 255.255.255.255 On-link 192.168.206.1 4501
224.0.0.0 240.0.0.0 On-link 127.0.0.1 4531
224.0.0.0 240.0.0.0 On-link 192.168.1.64 4502
224.0.0.0 240.0.0.0 On-link 192.168.206.1 4502
224.0.0.0 240.0.0.0 On-link 192.168.112.1 4502
224.0.0.0 240.0.0.0 On-link 172.16.1.136 21
255.255.255.255 255.255.255.255 On-link 127.0.0.1 4531
255.255.255.255 255.255.255.255 On-link 192.168.1.64 4501
255.255.255.255 255.255.255.255 On-link 192.168.206.1 4501
255.255.255.255 255.255.255.255 On-link 192.168.112.1 4501
255.255.255.255 255.255.255.255 On-link 172.16.1.136 276
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